Posted by www.textilesindepth.com
Glossary of Various Synthetic Fibers
Most synthetic manufactured fibers are created by "extrusion" - forcing a thick, viscous liquid (about the consistency of cold honey) through the tiny holes of a device called a spinneret to form continuous filaments of semi-solid polymer.
In their initial state, the fiber-forming polymers are solids and therefore must be first converted into a fluid state for extrusion. This is usually achieved by melting, if the polymers are thermoplastic synthetics (i.e., they soften and melt when heated), or by dissolving them in a suitable solvent if they are non-thermoplastic cellulosics. If they cannot be dissolved or melted directly, they must be chemically treated to form soluble or thermoplastic derivatives.
Recent technologies have been developed for some specialty fibers made of polymers that do not melt, dissolve, or form appropriate derivatives. For these materials, the small fluid molecules are mixed and reacted to form the otherwise intractable polymers during the extrusion process
Nylon
Nylon is a generic designation for a family of synthetic polymers known generically as polyamides and first produced on February 28, 1935 by Wallace Carothers at DuPont. Nylon is one of the most commonly used polymers
- Density - 1.15g/cm³
- Electrical conductivity (σ) - 10-12S/m
- Thermal conductivity 0.25W/(m·K), 463 K-624 K
- Melting point 190°C-350°C or 374°F-663°F
Overview
- Nylon is a thermoplastic silky material, first used commercially in a nylon-bristled toothbrush (1938), followed more famously by women's stockings ("nylons"; 1940). It is made of repeating units linked by peptide bonds (another name for amide bonds) and is frequently referred to as polyamide (PA). Nylon was the first commercially successful synthetic polymer. There are two common methods of making nylon for fiber applications. In one approach, molecules with an acid (COOH) group on each end are reacted with molecules containing amine (NH2) groups on each end. The resulting nylon is named on the basis of the number of carbon atoms separating the two acid groups and the two amines. These are formed into monomers of intermediate molecular weight, which are then reacted to form long polymer chains.
Nylon was intended to be a synthetic replacement for silk and substituted for it in many different products after silk became scarce during World War II. It replaced silk in military applications such as parachutes and flak vests, and was used in many types of vehicle tires.
Nylon fibers are used in many applications, including fabrics, bridal veils, carpets, musical strings, and rope.
Solid nylon is used for mechanical parts such as machine screws, gears and other low- to medium-stress components previously cast in metal. Engineering-grade nylon is processed by extrusion, casting, and injection molding. Solid nylon is used in hair combs. Type 6/6 Nylon 101 is the most common commercial grade of nylon, and Nylon 6 is the most common commercial grade of molded nylon. Nylon is available in glass-filled variants which increase structural and impact strength and rigidity, and molybdenum sulfide-filled variants which increase lubricity.
Chemistry
- Nylons are condensation copolymers formed by reacting equal parts of a diamine and a dicarboxylic acid, so that peptide bonds form at both ends of each monomer in a process analogous to polypeptide biopolymers.
Chemical elements included are carbon, hydrogen, nitrogen, and oxygen. The numerical suffix specifies the numbers of carbons donated by the monomers; the diamine first and the diacid second. The most common variant is nylon 6-6 which refers to the fact that the diamine (hexamethylene diamine) and the diacid (adipic acid) each donate 6 carbons to the polymer chain. As with other regular copolymers like polyesters and polyurethanes, the "repeating unit" consists of one of each monomer, so that they alternate in the chain. Since each monomer in this copolymer has the same reactive group on both ends, the direction of the amide bond reverses between each monomer, unlike natural polyamide proteins which have overall directionality: Cterminal→ Nterminal.
In the laboratory, nylon6-6 can also be made using adipoyl chloride instead of adipic. It is difficult to get the proportions exactly correct, and deviations can lead to chain termination at molecular weights less than a desirable 10,000 daltons (u). To overcome this problem, a crystalline, solid "nylon salt" can be formed at room temperature, using an exact 1:1 ratio of the acid and the base to neutralize each other. Heated to 285 °C, the salt reacts to form nylon polymer. Above 20,000 daltons, it is impossible to spin the chains into yarn, so to combat this, some acetic acid is added to react with a free amine end group during polymer elongation to limit the molecular weight. In practice, and especially for 6,6, the monomers are often combined in a water solution. The water used to make the solution is evaporated under controlledconditions, and the increasing concentration of "salt" is polymerized to the final molecular weight.
DuPont patented[1] nylon6,6, so in order to compete, other companies (particularly the German BASF) developed the homopolymer nylon6, or polycaprolactam - not a condensation polymer, but formed by a ring-opening polymerization (alternatively made by polymerizing aminocaproic acid). The peptide bond within the caprolactam is broken with the exposed active groups on each side being incorporated into two new bonds as the monomer becomes part of the polymer backbone. In this case, all amide bonds lie in the same direction, but the properties of nylon6 are sometimes indistinguishable from those of nylon6,6 - except for melt temperature (N6 is lower) and some fiber properties in products like carpets and textiles. There is also nylon9.
Nylon5,10, made from pentamethylene diamine and sebacic acid, was studied by Carothers even before nylon6,6 and has superior properties, but is more expensive to make. In keeping with this naming convention, "nylon6,12" (N-6,12) or "PA-6,12" is a copolymer of a 6C diamine and a 12C diacid. Similarly for N-5,10 N-6,11; N-10,12, etc. Other nylons include copolymerized dicarboxylic acid/diamine products that are not based upon the monomers listed above. For example, some aromatic nylons are polymerized with the addition of diacids like terephthalic acid (→ Kevlar) or isophthalic acid (→ Nomex), more commonly associated with polyesters. There are copolymers of N-6,6/N6; copolymers of N-6,6/N-6/N-12; and others. Because of the way polyamides are formed, nylon would seem to be limited to unbranched, straight chains. But "star" branched nylon can be produced by the condensation of dicarboxylic acids with polyamines having three or more amino groups.
Basic Concepts of Nylon Production
The first approach:
- combining molecules with an acid (COOH) group on each end are reacted with two chemicals that contain amine (NH2) groups on each end.
This process creates nylon 6,6, made of hexamethylene diamine with six carbon atoms and acidipic acid, as well as six carbon atoms.
The second approach:
- a compound has an acid at one end and an amine at the other and is polymerized to form a chain with repeating units of (-NH-[CH2]n-CO-)x.
- In other words, nylon 6 is made from a single six-carbon substance called caprolactam.
- In this equation, if n=5, then nylon 6 is the assigned name. (may also be referred to as polymer)
Nylon 6,6
- Pleats and creases can be heat-set at higher temperatures
- Nylon 6 is very easy to dye, but Nylon 6,6 is not
Nylon 6
- Better dye Affinity
- Softer Hand
Characteristics
- Variation of luster: nylon has the ability to be very lustrous, semilustrous or dull.
- Durability: its high tenacity fibers are used for seatbelts, tire cords, ballistic cloth and other uses.
- High elongation
- Excellent abrasion resistance
- Highly resilient (nylon fabrics are heat-set)
- Paved the way for easy-care garments
- High resistance to: insects, fungi and animals,molds, mildew, rot,many chemicals
- Used in carpets and nylon stockings
- Melts instead of burning
- Used in many military applications
Spandex
- Spandex-or elastane-is a synthetic fiber known for its exceptional elasticity. It is stronger and more durable than rubber, its major non-synthetic competitor. It was invented in 1959 by DuPont chemist Joseph Shivers. When first introduced, it revolutionized many areas of the clothing industry.
"Spandex" is a generic name and not derived from the chemical name of the fiber, as are most manufactured fibers, but an extension of the word expand."Spandex" is the preferred name in North America; elsewhere it is referred to as "elastane"
Spandex fiber production
- Spandex fibers are produced in four different ways, including melt extrusion, reaction spinning, solution dry spinning, and solution wet spinning. All of these methods include the initial step of reacting monomers to produce a prepolymer. Once the prepolymer is formed, it is reacted further in various ways and drawn out to produce a long fiber. The solution dry spinning method is used to produce over 90% of the world's spandex fibers.
Solution dry spinning
- Step 1: The first step is to produce the prepolymer. This is done by mixing a macroglycol with a diisocyanate monomer. The two compounds are mixed together in a reaction vessel to produce a prepolymer. A typical ratio of glycol to diisocyanate is 1:2.
- Step 2: The prepolymer is further reacted with an equal amount of diamine. This reaction is known as chain extension reaction. The resulting solution is diluted with a solvent to produce the spinning solution. The solvent helps make the solution thinner and more easily handled, and then it can be pumped into the fiber production cell.
- Step 3: The spinning solution is pumped into a cylindrical spinning cell where it is cured and converted into fibers. In this cell, the polymer solution is forced through a metal plate called a spinneret. This causes the solution to be aligned in strands of liquid polymer. As the strands pass through the cell, they are heated in the presence of a nitrogen and solvent gas. This process causes the liquid polymer to react chemically and form solid strands.
- Step 4: As the fibers exit the cell, an amount of solid strands are bundled together to produce the desired thickness. Each fiber of spandex is made up of many smaller individual fibers that adhere to one another due to the natural stickiness of their surface.
- Step 5: The resulting fibers are then treated with a finishing agent which can be magnesium stearate or another polymer. This treatment prevents the fibers' sticking together and aids in textile manufacture. The fibers are then transferred through a series of rollers onto a spool.
- Step 6: When the spools are filled with fiber, they are put into final packaging and shipped to textile manufacturers.
Major spandex fiber uses
- Apparel and clothing articles where stretch is desired, generally for comfort and fit, such as:
- athletic, aerobic, and exercise apparel
- wetsuitss
- wimsuits/bathing suits
- competitive swimwear
- netball bodysuits
- brassiere straps and bra side panels
- ski pants
- disco jeanss
- lacks
- hosiery
- leggings
- socks
- diapers
- skinny jeans
- belts
- underwear
- dance belts worn by male ballet dancers and others
- Compression garments such as:
- surgical hose
- support hose
- cycling shorts
- wrestling singlet
- one piece rowing suits
- foundation garments
- motion capture suits
- Shaped garments such as
- bra cups
Home furnishings, such as microbead pillows
- Spandex Fiber Characteristics
- Can be stretched repeatedly and still recover to very near its original length and shape
- Generally, can be stretched more than 500% without breaking
- Stronger, more durable and higher retractive force than rubber
- Lightweight, soft, smooth, supple
- In garments, provides a combination of comfort and fit, prevents bagging and sagging
- Heat-settable - facilitates transforming puckered fabrics into flat fabrics, or flat fabrics into permanent rounded shapes
- Dyeable
- Resistant to deterioration by body oils, perspiration, lotions or detergents
- Abrasion resistant
- When fabrics containing spandex are sewn, the needle causes little or no damage from "needle cutting" compared to the older types of elastic materials
- Available in fiber diameters ranging from 10 denier to 2500 denier
- Available in clear and opaque lusters
Acrylic
Basic Principles of Acrylic Fiber Production
- Acrylic fibers are produced from acrylonitrile, a petrochemical. The acrylonitrile is usually combined with small amounts of other chemicals to improve the ability of the resulting fiber to absorb dyes. Some acrylic fibers are dry spun and others are wet spun. Acrylic fibers are used in staple or tow form.
- Acrylic Fiber Characteristics
- Outstanding wickability & quick drying to move moisture from body surface
- Flexible aesthetics for wool-like, cotton-like, or blended appearance
- Easily washed, retains shape
- Resistant to moths, oil, and chemicals
- Dyeable to bright shades with excellent fastness
- Superior resistance to sunlight degradation
Some Major Acrylic Fiber Uses
- Apparel: Sweaters, socks, fleece wear, circular knit apparel, sportswear and childrens wear
- Home Furnishings: Blankets, area rugs, upholstery, pile; luggage, awnings, outdoor furniture
- Other Uses: Craft yarns, sail cover cloth, wipe cloths
- Industrial Uses: Asbestos replacement; concrete and stucco reinforcement
Aramid
- Aramid fibers are a class of heat-resistant and strong synthetic fibers. They are used in aerospace and military applications, for ballistic rated body armor fabric, and as an asbestos substitute. The name is a shortened form of "aromatic polyamide". They are fibers in which the chain molecules are highly oriented along the fiber axis, so the strength of the chemical bond can be exploited.
History
- Aromatic polyamides were first introduced in commercial applications in the early 1960s, with a meta-aramid fiber produced by DuPont under the tradename Nomex. This fiber, which handles similarly to normal textile apparel fibers, is characterized by its excellent resistance to heat, as it neither melts nor ignites in normal levels of oxygen. It is used extensively in the production of protective apparel, air filtration, thermal and electrical insulation as well as a substitute for asbestos. Meta-aramid is also produced in the Netherlands and Japan by Teijin under the tradename Teijinconex, in China by Yantai under the tradename New Star and a variant of meta-aramid in France by Kermel under the tradename Kermel.
Based on earlier research by Monsanto and Bayer, a fiber - para-aramid - with much higher tenacity and elastic modulus was also developed in the 1960s-1970s by DuPont and Akzo Nobel, both profiting from their knowledge of rayon, polyester and nylon processing.
Polymer preparation
- Aramids are generally prepared by the reaction between an amine group and a carboxylic acid halide group. Simple AB homopolymers may look like:
nNH2-Ar-COCl → -(NH-Ar-CO)n- + nHCl
The most well-known aramids (Nomex, Kevlar, Twaron and New Star) are AABB polymers. Nomex, New Star and Teijinconex contain predominantly the meta-linkage and are poly-metaphenylene isophtalamides (MPIA). Kevlar and Twaron are both p-phenylene terephtalamides (PPTA), the simplest form of the AABB para-polyaramide. PPTA is a product of p-phenylene diamine (PPD) and terephtaloyl dichloride (TDC or TCl). Production of PPTA relies on a co-solvent with an ionic component (calcium chloride (CaCl2)) to occupy the hydrogen bonds of the amide groups, and an organic component (N-methyl pyrrolidone (NMP)) to dissolve the aromatic polymer. Prior to the invention of this process by Leo Vollbracht, who worked at the Dutch chemical firm Akzo, no practical means of dissolving the polymer was known. The use of this system led to a patent war between Akzo and DuPont.
Spinning
- After production of the polymer, the aramid fiber is produced by spinning the solved polymer to a solid fiber from a liquid chemical blend. Polymer solvent for spinning PPTA is generally 100% (water free) sulfuric acid (H2SO4).
Appearances
- Fiber,Chopped fiber,Powder, Pulp
- Aramid fiber characteristics
- good resistance to abrasion
- good resistance to organic solvents
- nonconductive
- no melting point, degradation starts from 500°C
- low flammability
- good fabric integrity at elevated temperatures
- sensitive to acids and salts
- sensitive to ultraviolet radiation
- prone to static build-up unless finished
Major industrial uses
- flame-resistant clothing
- heat protective clothing and helmets
- body armor, competing with PE based fiber products such as Dyneema and Spectra
- composite materials
- asbestos replacement (e.g. braking pads)
- hot air filtration fabrics
- tires, newly as Sulfron (sulfur modified Twaron)
- mechanical rubber goods reinforcement
- ropes and cables
- wicks for fire dancing
- optical fiber cable systems
- sail cloth (not necessarily racing boat sails)
- sporting goods
- drumheads
- wind instrument reeds, such as the Fibracell
- brandspeaker woofers
- boathull material
- fiber reinforced concrete
- reinforced thermoplastic pipes
- tennis strings (e.g. by Ashaway and Prince tennis companies)
- hockey sticks (normally in composition with such materials as wood and carbon)
Polyurethane
- A polyurethane, commonly abbreviated PU, is any polymer consisting of a chain of organic units joined by urethane (carbamate) links. Polyurethane polymers are formed through step-growth polymerization by reacting a monomer containing at least two isocyanate functional groups with another monomer containing at least two hydroxyl (alcohol) groups in the presence of a catalyst.
Raw materials
- For the manufacture of polyurethane polymers, two groups of at least bifunctional substances are needed as reactants; compounds with isocyanate groups, and compounds with active hydrogen atoms. The physical and chemical character, structure, and molecular size of these compounds influence the polymerization reaction, as well as ease of processing and final physical properties of the finished polyurethane. In addition, additive such as catalysts, surfactants, blowing agents, cross linkers, flame retardants, light stabilizers, and fillers are used to control and modify the reaction process and performance characteristics of the polymer.
Production
- The main polyurethane producing reaction is between a diisocyanate (aromatic and aliphatic types are available) and a polyol, typically a polypropylene glycol or polyester polyol, in the presence of catalysts and materials for controlling the cell structure, (surfactants) in the case of foams. Polyurethane can be made in a variety of densities and hardnesses by varying the type of monomer(s) used and adding other substances to modify their characteristics, notably density, or enhance their performance. Other additives can be used to improve the fire performance, stability in difficult chemical environments and other properties of the polyurethane products.
Though the properties of the polyurethane are determined mainly by the choice of polyol, the diisocyanate exerts some influence, and must be suited to the application. The cure rate is influenced by the functional group reactivity and the number of functional isocyanate groups. The mechanical properties are influenced by the functionality and the molecular shape. The choice of diisocyanate also affects the stability of the polyurethane upon exposure to light. Polyurethanes made with aromatic diisocyanates yellow with exposure to light, whereas those made with aliphatic diisocyanates are stable.[24]
Softer, elastic, and more flexible polyurethanes result when linear difunctional polyethylene glycol segments, commonly called polyether polyols, are used to create the urethane links. This strategy is used to make spandex elastomeric fibers and soft rubber parts, as well as foam rubber. More rigid products result if polyfunctional polyols are used, as these create a three-dimensional cross-linked structure which, again, can be in the form of a low-density foam.
An even more rigid foam can be made with the use of specialty trimerization catalysts which create cyclic structures within the foam matrix, giving a harder, more thermally stable structure, designated as polyisocyanurate foams. Such properties are desired in rigid foam products used in the construction sector.
Careful control of viscoelastic properties - by modifying the catalysts and polyols used -can lead to memory foam, which is much softer at skin temperature than at room temperature.
There are then two main foam variants: one in which most of the foam bubbles (cells) remain closed, and the gas(es) remains trapped, the other being systems which have mostly open cells, resulting after a critical stage in the foam-making process (if cells did not form, or became open too soon, foam would not be created). This is a vitally important process: if the flexible foams have closed cells, their softness is severely compromised, they become pneumatic in feel, rather than soft; so, generally speaking, flexible foams are required to be open-celled.
The opposite is the case with most rigid foams. Here, retention of the cell gas is desired since this gas (especially the fluorocarbons referred to above) gives the foams their key characteristic: high thermal insulation performance.
A third foam variant, called microcellular foam, yields the tough elastomeric materials typically experienced in the coverings of car steering wheels and other interior automotive components.
Manufacturing
- The methods of manufacturing polyurethane finished goods range from small, hand pour piece-part operations to large, high-volume bunstock and boardstock production lines. Regardless of the end-product, the manufacturing principle is the same: to meter the liquid isocyanate and resin blend at a specified stoichiometric ratio, mix them together until a homogeneous blend is obtained, dispense the reacting liquid into a mold or on to a surface, wait until it cures, then demold the finished part.
Dispense Equipment Although the capital outlay can be high, it is desirable to use a meter-mix or dispense unit for even low-volume production operations that require a steady output of finished parts. Dispense equipment consists of material holding (day) tanks, metering pumps, a mix head, and a control unit. Often, a conditioning or heater-chiller unit is added to control material temperature in order to improve mix efficiency, cure rate, and to reduce process variability. Choice of dispense equipment components depends on shot size, throughput, material characteristics such as viscosity and filler content, and process control.
Material day tanks may be single to hundreds of gallons in size, and may be supplied directly from drums, IBCs (intermediate bulk containers, such as totes), or bulk storage tanks. They may incorporate level sensors, conditioning jackets, and mixers. Pumps can be sized to meter in single grams per second up to hundreds of pounds per minute. They can be rotary, gear, or piston pumps, or can be specially hardened lance pumps to meter liquids containing highly abrasive fillers such as wollastonite.
The pumps can drive low-pressure (10 to 30 bar) or high-pressure (125 to 200 bar) dispense systems. Mix heads can be simple static mix tubes, rotary element mixers, low-pressure dynamic mixers, or high-pressure hydraulically actuated direct impingement mixers. Control units may have basic on/off - dispense/stop switches, and analogue pressure and temperature gages, or may be computer controlled with flow meters to electronically calibrate mix ratio, digital temperature and level sensors, and a full suite of statistical process control software. Add-ons to dispense equipment include nucleation or gas injection units, and third or fourth stream capability for adding pigments or metering in supplemental additive packages.
Tooling
- Distinct from pour-in-place, bun and boardstock, and coating applications, the production of piece parts requires some type of tooling to contain and form the reacting liquid. The choice of mold making material is dependent on the expected number of uses to end-of-life (EOL), molding pressure, flexibility, and heat transfer characteristics. RTV silicone is used for tooling that has an EOL in the thousands of parts. It is typically used for molding rigid foam parts, where the ability to stretch and peel the mold around undercuts is needed.
The heat transfer characteristic of RTV silicone tooling is poor. High-performance flexible polyurethane elastomers are also used in this way. Epoxy, metal-filled epoxy, and metal-coated epoxy is used for tooling that has an EOL in the tens-of-thousands of parts. It is typically used for molding flexible foam cushions and seating, integral skin and microcellular foam padding, and shallow-draft RIM bezels and fascia. The heat transfer characteristic of epoxy tooling is fair; the heat transfer characteristic of metal-filled and metal-coated epoxy is good. Copper tubing can be incorporated into the body of the tool, allowing hot water to circulate and heat the mold surface.
Aluminum is used for tooling that has an EOL in the hundreds-of-thousands of parts. It is typically used for molding microcellular foam gasketing and cast elastomer parts, and is milled or extruded into shape. Mirror finish stainless steel is used for tooling that imparts a glossy appearance to the finished part. The heat transfer characteristic of metal tooling is excellent. Finally, molded or milled polypropylene is used to create low-volume tooling for molded gasket applications. Instead of many expensive metal molds, low-cost plastic tooling can be formed from a single metal master, which also allows greater design flexibility. The heat transfer characteristic of polypropylene tooling is poor, which must be taken into consideration during the formulation process.
Polyurethane uses
- Polyurethane products have many uses. Over three quarters of the global consumption of polyurethane products is in the form of foams, with flexible and rigid types being roughly equal in market size. In both cases, the foam is usually behind other materials:
- Flexible foams are behind upholstery fabrics in commercial and domestic furniture
- Rigid foams are inside the metal and plastic walls of most refrigerators and freezers, or behind paper, metals and other surface materials in the case of thermal insulation panels in the construction sector.
Its use in garments is growing:
- In lining the cups of brassieres.
- Polyurethane is also used for moldings which include door frames, columns, balusters, window headers, pediments, medallions and rosettes.
- Polyurethane is also used in the concrete construction industry to create formliners. Polyurethane formliners serves as a mold for concrete, creating a variety of textures and art.
The precursors of expanding polyurethane foam are available in many forms, for use in insulation, sound deadening, flotation, industrial coatings, packing material, and even cast-in-place upholstery padding. Since they adhere to most surfaces and automatically fill voids, they have become quite popular in these applications